A peapod-like ZnO@C design with internal void space to relieve its large-volume-change as lithium-ion battery anode

Peapod-like ZnO@C with internal void space has been synthesized by calcination of ZnO/ZnOHF@polydopamine nanorods. By designing both the large void space between particles and external elastic carbon shell, the large volume change of ZnO during charge-discharge process could be effectively relieved. Moreover, the carbon shell functioned as an electronic conductor and elastic barrier, could accelerate the reaction kinetics and confine stable SEI films formation on the outer protective layer to further improve the structural integrity. Benefiting from these structure advantages, the peapod-like ZnO@C presents a prominent electrochemical performance with a retained discharge capacity of 565.1 mA h g^?1 at 0.2 A g^?1 and high rate capacity of 246.6 mA h g^?1 even at 4 A g^?1.     

Novel barium titanate based ferroelectric relaxor ceramics with superior charge-discharge performance

Lead-free 0.9BaTiO₃-0.1(Bi_0.9Na_0.1)(In_0.8Zr_0.2)O₃ (0.9BT-0.1BNIZ) ferroelectric relaxor ceramic was synthesized by solid-state reaction method. A dense microstructure and fine grain size was obtained with addition of BNIZ content. The dielectric behaviors indicated the dominance of ergodic relaxor phase. The 0.9BT-0.1BNIZ ceramic was found to possess an enhanced recoverable energy density (W_R～1.33?J/cm³) and efficiency (η～88%) under 18?kV/mm at room temperature. What’s more, W_R is maintained ≥0.53?J/cm³ with η?≥?94% under 10?kV/mm and the variation of W_R is less than 15% over 25～140?°C. The high stability of energy storage properties is mainly ascribed to the characteristics of ergodic relaxor phase. The stored energy was released in sub-microseconds (～0.19?μs). The superior current density (C_D～796?A/cm²) and the power density (P_D～39.8?MW/cm³) were obtained simultaneously. The enhanced W_R and the superior charge-discharge performances strongly demonstrate that the BT-based ceramics are promising candidates of high-power pulse capacitor applications.     

Ferroelastic domain structure and phase transition in single-crystalline [PbZn1/3Nb2/3O3]1-x[PbTiO3]x observed via in situ x-ray microbeam

(1-x)Pb(Zn_1/3Nb_2/3)O₃-xPbTiO₃ ((1-x)PZN-xPT in short) is one of the most important piezoelectric materials. In this work, we extensively investigated (1-x)PZN-xPT (x = 0.07–0.11) ferroelectric single crystals using in-situ synchrotron μXRD, complemented by TEM and PFM, to correlate microstructures with phase transitions. The results reveal that (i) at 25 °C, the equilibrium state of (1-x)PZN-xPT is a metastable orthorhombic phase for x = 0.07 and 0.08, while it shows coexistence of orthorhombic and tetragonal phases for x = 0.09 and x = 0.11, with all ferroelectric phases accompanied by ferroelastic domains; (ii) upon heating, the phase transformation in x = 0.07 is Orthorhombic → Monoclinic → Tetragonal → Cubic. The coexistence of ferroelectric tetragonal and paraelectric cubic phases was in-situ observed in x = 0.08 above Curie temperature (T_C), and (iii) phase transition can be explained by the evolution of the ferroelectric and ferroelastic domains. These results disclose that (1-x)PZN-xPT are in an unstable regime, which is possible factor for its anomalous dielectric response and high piezoelectric coefficient.     

Isothermal crystallization kinetics and subsequent melting behavior of β‐nucleated isotactic polypropylene/graphene oxide composites with different ordered structure

The effects of ordered structure on isothermal crystallization kinetics and subsequent melting behavior of β‐nucleated isotactic polypropylene/graphene oxide (iPP/GO) composites were studied using differential scanning calorimetry. The ordered structure status was controlled by tuning the fusion temperature (T_f). The results showed that depending on the variation of crystallization rate, the whole T_f range could be divided into three regions: Region I (T_f > 179 °C), Region II (170 °C ≤ T_f ≤ 179 °C) and Region III (T_f < 170 °C). As T_f decreased from Region I to Region III, the crystallization rate would increase substantially at two transition points, due to the variation of the ordered structure status. Calculation of Avrami exponent n indicated that the ordered structure induced the formation of two‐dimensional growing crystallites rather than three‐dimensional growing crystallites. Moreover, in the case of isothermal crystallization, the ordered structure effect (OSE) can also greatly increase the relative content of β‐phase (β_c). In Region II, OSE took place, resulting in evident increase of β_c, achieving 92.4% at maximum. The variation of the isothermal crystallization temperature (T_iso) had little influence on the T_f range (Region II) of the OSE. The higher T_f in Region II was more favorable for the formation of higher β_c. The ordered structure was favorable for the improvement of the nucleating efficiency of β‐nucleating agent (β‐NE), and was more effective for the improvement of lower β‐NE. © 2018 Society of Chemical Industry     

Multi-Purpose Forensics of Image Manipulations Using Residual- Based Feature

The multi-purpose forensics is an important tool for forge image detection. In this paper, we propose a universal feature set for the multi-purpose forensics which is capable of simultaneously identifying several typical image manipulations, including spatial low-pass Gaussian blurring, median filtering, re-sampling, and JPEG compression. To eliminate the influences caused by diverse image contents on the effectiveness and robustness of the feature, a residual group which contains several highpass filtered residuals is introduced. The partial correlation coefficient is exploited from the residual group to purely measure neighborhood correlations in a linear way. Besides that, we also combine autoregressive coefficient and transition probability to form the proposed composite feature which is used to measure how manipulations change the neighborhood relationships in both linear and non-linear way. After a series of dimension reductions, the proposed feature set can accelerate the training and testing for the multipurpose forensics. The proposed feature set is then fed into a multi-classifier to train a multi-purpose detector. Experimental results show that the proposed detector can identify several typical image manipulations, and is superior to the complicated deep CNN-based methods in terms of detection accuracy and time efficiency for JPEG compressed image with low resolution.     

户内热转印粉末涂料用混合型聚酯树脂的合成研究

通过分析热转印性能的影响因素合成了不同结构的聚酯树脂，研究了树脂酸值对热转印性能的影响，同时研究了部分单体对聚酯树脂热转印性能的影响。采用 DSC热分析法研究了固化促进剂对粉末涂料固化行为的影响，结果表明：选择合适的固化促进剂对涂层转印性能的提高有至关重要的作用。     

垂直钻井并联调整装备的设计与分析

针对当前大型钻井垂直调整技术有限的状况,设计了一种适用于垂直钻井条件下的12输入6自由度并联调整装备。该装备机构具有6个结构对称的冗余支链,每个支链由复合转动副和复合球副组成,复合转动副与复合球副间通过两个移动副连接。基于ANSYS软件对机构进行模态分析,得到动平台前6阶频率分布和模态振型,以及动平台沿着X、Y、Z方向的位移频响。结果表明,动平台对46Hz频率的外力最为敏感。此外,采用三维搜索法确定了6自由度平台的工作空间,对分析参数对整个机构的影响关系及优化参数具有借鉴意义。